The class of nitrogen-containing molecules called diazo compounds has revealed a hidden talent: coupling with certain diazo partners to form carbon-carbon double bonds (Angew. Chem. Int. Ed., DOI: ...
Metal-free carbon–carbon bond-forming reductive coupling between boronic acids and tosylhydrazones
The formation of carbon–carbon bonds is a fundamental transformation in organic synthesis. In spite of the myriad methods available, advantageous methodologies in terms of selectivity, availability of ...
IN 1915, Karrer 1 put forward the view that the coupling of aromatic tertiary amines with diazo-compounds to form alkylamino azo-compounds takes place through the preliminary combination of the ...
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